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Beilstein J. Org. Chem. 2011, 7, 555–564, doi:10.3762/bjoc.7.64
Graphical Abstract
Figure 1: Monodentate NHCs with sterically hindered N-substituents.
Figure 2: NHCs with axially chiral biaryl frameworks.
Scheme 1: Synthesis of N-heterocyclic carbene precursor.
Scheme 2: Synthesis of mono(NHC)–Pd(II) complex.
Figure 3: ORTEP drawing of NHC–Pd(II) complex (S)-7a with thermal ellipsoids at the 30% probability level. Se...
Scheme 3: Synthesis of mono(NHC)–Au(I) complex.
Figure 4: ORTEP drawing of NHC–Au(I) complex (S)-6a with thermal ellipsoids at the 30% probability level. Sel...
Scheme 4: Synthesis of mono(NHC)–Au(I) complex (S)-6b.
Scheme 5: Synthesis of mono(NHC)–Au(I) complex (S)-6c.
Scheme 6: The application of catalysts (S)-6b and 6c in the intramolecular hydroamination reaction.